Sulfide-Induced Dimerization Versus Demetallation of Tricopper(I) Clusters Protected by Tris-Thiolato Metalloligands

Goo, Zi Lang; Yoshinari, Nobuto; Yasukawa, Yuhei et al.

Chemistry - An Asian Journal, 2024, 19(13), e202400266

Number of Access:346（2025-08-20 22:57 Counts）

Identifier to cite or link to this item: https://hdl.handle.net/11094/97146

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Title
Sulfide-Induced Dimerization Versus Demetallation of Tricopper(I) Clusters Protected by Tris-Thiolato Metalloligands
Creator
CreatorName
Goo, Zi Lang
NRID
1000010583338 1000010583338
ORCID
0000-0003-2457-0967 0000-0003-2457-0967
researchmap permalink
read0151149 read0151149
Scopus Author ID
14009212400 14009212400
CreatorName
Yoshinari, Nobuto
CreatorName
Yasukawa, Yuhei
CreatorName
Minami, Katsue
NRID
1000050201497 1000050201497
researchmap permalink
takumikonno takumikonno
Scopus Author ID
7202325347 7202325347
CreatorName
Konno, Takumi
Subject
copper cluster
metalloligand
S ligand
structural conversion
sulfide ion
Description
Goo Z.L., Yoshinari N., Yasukawa Y., et al. Sulfide-Induced Dimerization Versus Demetallation of Tricopper(I) Clusters Protected by Tris-Thiolato Metalloligands. Chemistry - An Asian Journal 19, e202400266 (2024); https://doi.org/10.1002/asia.202400266.
Abstract
Here, we report the reactivity of copper(I) clusters toward sulfide ions; these sulfide copper(I) clusters have attracted much attention due to their relevance to biologically active centers and their fascinating structural and photophysical properties. Treatment of the CuI3RhIII2 pentanuclear complex, [Cu3{Rh(aet)3}2]3+ (aet=2-aminoethanethiolate), in which a {CuI3}3+ cluster moiety is bound by two fac-[Rh(aet)3] metalloligands, with NaSH in water produced the CuI6RhIII4 decanuclear complex, [Cu6S{Rh(aet)3}4]4+, accompanied by the dimerization of [Cu3{Rh(aet)3}2]3+ and the incorporation of a sulfide ion at the center. While similar treatment using the analogous CuI3IrIII2 complex with fac-[Ir(aet)3] metalloligands, [Cu3{Ir(aet)3}2]3+, produced the isostructural CuI6IrIII4 decanuclear complex, [Cu6S{Ir(aet)3}4]4+, the use of the CuI3RhIII2 complex with fac-[Rh(apt)3] metalloligands, [Cu3{Rh(apt)3}2]3+ (apt=3-aminopropanethiolate), resulted in the removal of one of the three CuI atoms from {CuI3}3+ to afford the CuI2RhIII2 tetranuclear complex, [Cu2{Rh(apt)3}2]2+.
Publisher
John Wiley and Sons Ltd
Source Title
Chemistry - An Asian Journal
Volume (Issue)
19(13)
Page
e202400266
Date of Issued
2024-07-02
Language
English
Handle URL
https://hdl.handle.net/11094/97146
PISSN
18614728
eISSN
1861471X
Relation.isIdenticalTo
DOI (Publisher Version)
https://doi.org/10.1002/asia.202400266
Access Rights
open access
CopyRight
This article is licensed under a Creative Commons Attribution 4.0 International License.
oaire:version
Version of Record
Category
学術雑誌論文 Journal Article