Control of sulfur number in sulfur-containing compounds: the effect of base type, equivalent of the base, and reaction solvent in synthesizing linear sulfur

Nishimura, Ryuto; Kobayashi, Yuichiro; Kamioka, Ryunosuke; Hashimoto, Shun; Yamaguchi, Hiroyasu

doi:https://doi.org/10.1093/chemle/upae105

Control of sulfur number in sulfur-containing compounds: the effect of base type, equivalent of the base, and reaction solvent in synthesizing linear sulfur

Nishimura, Ryuto; Kobayashi, Yuichiro; Kamioka, Ryunosuke et al.

Chemistry Letters, 2024, 53(6), upae105

Number of Access:549（2025-07-24 04:14 Counts）

Identifier to cite or link to this item: https://hdl.handle.net/11094/97747

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Title	Control of sulfur number in sulfur-containing compounds: the effect of base type, equivalent of the base, and reaction solvent in synthesizing linear sulfur
Creator	CreatorName Nishimura, Ryuto
	NRID 1000010739676 1000010739676 ORCID 0000-0002-9967-5520 0000-0002-9967-5520 researchmap permalink kobayashiy kobayashiy Scopus Author ID 14060575800 14060575800 CreatorName Kobayashi, Yuichiro
	CreatorName Kamioka, Ryunosuke
	CreatorName Hashimoto, Shun
	NRID 1000000314352 1000000314352 ORCID 0000-0002-4801-5071 0000-0002-4801-5071 researchmap permalink HiroyasuYamaguchi HiroyasuYamaguchi Scopus Author ID 7404273473 7404273473 CreatorName Yamaguchi, Hiroyasu
Subject	sulfur
Subject	sulfur-containing compounds
Description	This is a pre-copyedited, author-produced version of an article accepted for publication in Chemistry Letters following peer review. The version of record Nishimura R., Kobayashi Y., Kamioka R., et al. Control of sulfur number in sulfur-containing compounds: the effect of base type, equivalent of the base, and reaction solvent in synthesizing linear sulfur. Chemistry Letters 53, upae105 (2024); is available online at: https://doi.org/10.1093/chemle/upae105.
Abstract	Since the properties of sulfur-containing compounds depend on the number of sulfur atoms (sulfur number) contained in the compounds, it is desirable to develop a method to control the sulfur number. A common method for synthesizing sulfur-containing compounds is to mix sulfur with a base to form linear sulfur, which is then reacted with an organic compound to obtain a sulfur-containing compound. In this study, we systematically investigated the relationships between the type of base, equivalent amount of base, the reaction solvent, and the sulfur number in the resulting sulfur-containing compound. The sulfur numbers of sulfur-containing compounds prepared in water were controlled by the equivalent ratio of elemental sulfur (S8) and base. Sulfur-containing compounds with high sulfur values were obtained using solvents with low dielectric constants and with lower base equivalents compared to S8
Publisher	Chemical Society of Japan
Source Title	Chemistry Letters
Volume (Issue)	53(6)
Page	upae105
Date of Issued	2024-06-01
Language	English
Handle URL	https://hdl.handle.net/11094/97747
PISSN	03667022
eISSN	13480715
Relation.isVersionOf	DOI (Publisher Version) https://doi.org/10.1093/chemle/upae105
Access Rights	open access
oaire:version	Accepted Manuscript
Category	学術雑誌論文 Journal Article

Resource Type	journal article
Local Type	Journal Article
DCTERMS.bibliographicCitation	Chemistry Letters. 2024, 53(6), p. upae105
DC.title	Control of sulfur number in sulfur-containing compounds: the effect of base type, equivalent of the base, and reaction solvent in synthesizing linear sulfur
DC.creator	Nishimura, Ryuto
	Kobayashi, Yuichiro
	Kamioka, Ryunosuke
	Hashimoto, Shun
	Yamaguchi, Hiroyasu
DC.publisher	Chemical Society of Japan
DC.language' scheme='DCTERMS.RFC1766	English
DCTERMS.issued' scheme='DCTERMS.W3CDTF	2024-06-01
DC.identifier	https://doi.org/10.1093/chemle/upae105
DC.subject	sulfur
DC.subject	sulfur-containing compounds
DC.description	This is a pre-copyedited, author-produced version of an article accepted for publication in Chemistry Letters following peer review. The version of record Nishimura R., Kobayashi Y., Kamioka R., et al. Control of sulfur number in sulfur-containing compounds: the effect of base type, equivalent of the base, and reaction solvent in synthesizing linear sulfur. Chemistry Letters 53, upae105 (2024); is available online at: https://doi.org/10.1093/chemle/upae105.
DCTERMS.abstract	Since the properties of sulfur-containing compounds depend on the number of sulfur atoms (sulfur number) contained in the compounds, it is desirable to develop a method to control the sulfur number. A common method for synthesizing sulfur-containing compounds is to mix sulfur with a base to form linear sulfur, which is then reacted with an organic compound to obtain a sulfur-containing compound. In this study, we systematically investigated the relationships between the type of base, equivalent amount of base, the reaction solvent, and the sulfur number in the resulting sulfur-containing compound. The sulfur numbers of sulfur-containing compounds prepared in water were controlled by the equivalent ratio of elemental sulfur (S8) and base. Sulfur-containing compounds with high sulfur values were obtained using solvents with low dielectric constants and with lower base equivalents compared to S8
DC.format	97747
citation_title	Control of sulfur number in sulfur-containing compounds: the effect of base type, equivalent of the base, and reaction solvent in synthesizing linear sulfur
citation_author	Nishimura, Ryuto
	Kobayashi, Yuichiro
	Kamioka, Ryunosuke
	Hashimoto, Shun
	Yamaguchi, Hiroyasu
citation_publisher	Chemical Society of Japan
citation_language	English
citation_date	2024-06-01
citation_journal_title	Chemistry Letters
citation_volume	53
citation_issue	6
citation_firstpage	upae105
citation_doi	https://doi.org/10.1093/chemle/upae105
citation_public_url	https://hdl.handle.net/11094/97747

Control of sulfur number in sulfur-containing compounds: the effect of base type, equivalent of the base, and reaction solvent in synthesizing linear sulfur

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