Transition Behaviors of Isostructural Hydrogen-Bonded Frameworks Composed of Naphthalene, Quinoxaline, and Pyrazinopyrazine Derivatives

Kubo, Haruka; Konishi, Shunsuke; Oketani, Ryusei et al.

Chemistry - A European Journal, 2024, 30(44), e202401645

Number of Access:44（2025-05-02 12:42 Counts）

Identifier to cite or link to this item: https://hdl.handle.net/11094/98295

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Title
Transition Behaviors of Isostructural Hydrogen-Bonded Frameworks Composed of Naphthalene, Quinoxaline, and Pyrazinopyrazine Derivatives
Creator
CreatorName
Kubo, Haruka
CreatorName
Konishi, Shunsuke
NRID
1000060874956 1000060874956
ORCID
0000-0001-7860-2456 0000-0001-7860-2456
researchmap permalink
ryuseioketani ryuseioketani
Scopus Author ID
57086955000 57086955000
CreatorName
Oketani, Ryusei
NRID
1000020222226 1000020222226
ORCID
0000-0002-2215-935X 0000-0002-2215-935X
researchmap permalink
20190602_Sun 20190602_Sun
Scopus Author ID
55735983400 55735983400
CreatorName
Hayashi, Takashi
NRID
1000090419466 1000090419466
ORCID
0000-0002-8170-5605 0000-0002-8170-5605
researchmap permalink
Ichiro_Hisaki Ichiro_Hisaki
Scopus Author ID
12801798700 12801798700
CreatorName
Hisaki, Ichiro
Subject
Crystal engineering
Flexibility
Hydrogen-bonded framework
Isostructure
Porous molecular crystal
Description
Kubo H., Konishi S., Oketani R., et al. Transition Behaviors of Isostructural Hydrogen-Bonded Frameworks Composed of Naphthalene, Quinoxaline, and Pyrazinopyrazine Derivatives. Chemistry - A European Journal 30, e202401645 (2024); https://doi.org/10.1002/chem.202401645.
Abstract
A series of isostructural reticular frameworks with systematic differences on chemical structures allows us to disclose correlations between specific structural factors and properties, providing insights for designing novel porous materials. However, even slight differences in the molecular structure often lead to non-isostructural polymorphic frameworks particularly in the case of hydrogen-bonded organic frameworks (HOFs) because the structures of HOFs are based on a subtle balance of reversible interactions. In this study, we found that three simple analogues of tetracarboxylic acids with naphthalene, quinoxaline, and pyrazinopyrazine cores (NT, QX, and PP, respectively) yielded isostructural solvated HOFs (NT-1, QX-1, and PP-1, respectively), where hydrogen-bonded sql-networked sheets were slip-stacked with closely similar manners. More importantly, these isostructural HOFs underwent structural transformations in different manners upon removal of the guest solvents. Comparison of the crystal structures of the HOFs before and after the transformation revealed that intermolecular interactions of the core significantly affected on rearrangements of hydrogen bonds in the transformation. The results suggest the potential to control the properties and functions of isostructural HOFs by elements in the core.
Publisher
John Wiley and Sons Inc
Source Title
Chemistry - A European Journal
Volume (Issue)
30(44)
Page
e202401645
Date of Issued
2024-08-06
Language
English
Handle URL
https://hdl.handle.net/11094/98295
PISSN
09476539
eISSN
15213765
Relation.isIdenticalTo
DOI (Publisher Version)
https://doi.org/10.1002/chem.202401645
Access Rights
open access
CopyRight
This article is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.
oaire:version
Version of Record
Category
学術雑誌論文 Journal Article