Reversible modulation of the local environment around metal centers bearing multifunctional carbenes

Yamauchi, Yasuhiro; Ogoshi, Sensuke; Uetake, Yuta et al.

Chemistry Letters, 2024, 53(3), upae042

Number of Access:539（2025-07-26 12:11 Counts）

Identifier to cite or link to this item: https://hdl.handle.net/11094/98569

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Title
Reversible modulation of the local environment around metal centers bearing multifunctional carbenes
Creator
CreatorName
Yamauchi, Yasuhiro
NRID
1000030252589 1000030252589
researchmap permalink
read0042792 read0042792
Scopus Author ID
7005303403 7005303403
CreatorName
Ogoshi, Sensuke
NRID
1000010755440 1000010755440
ORCID
0000-0002-4742-8085 0000-0002-4742-8085
researchmap permalink
yutauetake yutauetake
Scopus Author ID
56417952700 56417952700
CreatorName
Uetake, Yuta
NRID
1000030710074 1000030710074
ORCID
0000-0003-0882-6109 0000-0003-0882-6109
researchmap permalink
YHoshimoto YHoshimoto
Scopus Author ID
36463455400 36463455400
CreatorName
Hoshimoto, Yoichi
Subject
N-heterocyclic carbene
nickel complex
X-ray absorption spectroscopy in organic solvents
Description
Yamauchi Y., Ogoshi S., Uetake Y., et al. Reversible modulation of the local environment around metal centers bearing multifunctional carbenes. Chemistry Letters 53, upae042 (2024); https://doi.org/10.1093/chemle/upae042.
Abstract
This Highlight Review provides examples of external-stimuli-driven reversible modulations of the spatial, electronic, and magnetic environment around metal centers that bear multifunctional N-heterocyclic carbenes (NHCs). In particular, recent reports on Lewis-base- or Lewis-acid- mediated reversible molecular transformations of Ni(0) complexes that bear N-phosphine-oxide-substituted imidazolylidenes (PoxIms) and the corresponding imidazolinylidenes (SPoxIms) are spotlighted. We also discuss the utility of using X-ray absorption spectroscopy to examine the synthesized (S)PoxIm-Ni complexes to gain spectroscopic insight into the changes in the local environment and electronic state of the metal centers induced by these reversible transformations. Overall, this review highlights the multipurpose utility of multifunctional NHCs as a key to designing and reversibly modulating the local environment of metal centers, which paves the way for accomplishing hitherto challenging molecular transformations and developing unprecedented reactivity of multimetallic compounds.
Publisher
Chemical Society of Japan
Source Title
Chemistry Letters
Volume (Issue)
53(3)
Page
upae042
Date of Issued
2024-03-07
Language
English
Handle URL
https://hdl.handle.net/11094/98569
PISSN
03667022
eISSN
13480715
Relation.isIdenticalTo
DOI (Publisher Version)
https://doi.org/10.1093/chemle/upae042
Access Rights
open access
CopyRight
This article is licensed under a Creative Commons Attribution 4.0 International License.
oaire:version
Version of Record
Category
学術雑誌論文 Journal Article