Derivatization of sumanenetrione through Lewis acid-mediated Suzuki-Miyaura coupling and an unprecedented ring opening

Han, Junyi; Uetake, Yuta; Yakiyama, Yumi et al.

Chemical Communications, 2023, 59(31), 4632-4635

Number of Access:624（2025-07-31 17:05 Counts）

Identifier to cite or link to this item: https://hdl.handle.net/11094/98572

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Title
Derivatization of sumanenetrione through Lewis acid-mediated Suzuki-Miyaura coupling and an unprecedented ring opening
Creator
CreatorName
Han, Junyi
NRID
1000010755440 1000010755440
ORCID
0000-0002-4742-8085 0000-0002-4742-8085
researchmap permalink
yutauetake yutauetake
Scopus Author ID
56417952700 56417952700
CreatorName
Uetake, Yuta
NRID
1000060636819 1000060636819
ORCID
0000-0003-4278-2015 0000-0003-4278-2015
researchmap permalink
yumiyakiyama yumiyakiyama
Scopus Author ID
57195377416 57195377416
CreatorName
Yakiyama, Yumi
NRID
1000000262147 1000000262147
ORCID
0000-0001-5783-4151 0000-0001-5783-4151
researchmap permalink
read0184917 read0184917
Scopus Author ID
7402869823 7402869823
CreatorName
Sakurai, Hidehiro
Description
Han J., Uetake Y., Yakiyama Y., et al. Derivatization of sumanenetrione through Lewis acid-mediated Suzuki-Miyaura coupling and an unprecedented ring opening. Chemical Communications 59, 4632 (2023); https://doi.org/10.1039/d3cc00394a.
Abstract
A series of sumanenetrione derivatives were synthesized through Lewis acid-mediated Suzuki-Miyaura cross-coupling. Their optical properties reflected the significantly strong electron-accepting ability of sumanenetrione. The bowl strain of the 2-hydroxyphenyl derivative brought the ring-opening response adjacent to the substituent even at room temperature without any activation, which generally requires harsh conditions.
Publisher
Royal Society of Chemistry
Source Title
Chemical Communications
Volume (Issue)
59(31)
Page
4632-4635
Date of Issued
2023-03-15
Language
English
Handle URL
https://hdl.handle.net/11094/98572
PISSN
13597345
eISSN
1364548X
Relation.isIdenticalTo
DOI (Publisher Version)
https://doi.org/10.1039/d3cc00394a
Access Rights
open access
CopyRight
This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 International License.
oaire:version
Version of Record
Category
学術雑誌論文 Journal Article