Efficiency enhancement in mesogenic-phthalocyanine-based solar cells with processing additives

Dao, Quang Duy; Hori, Tetsuo; Hukumura, Kaoru; Masuda, Tetsuya; Kamikado, Toshiya; Fujii, Akihiko; Shimizu, Yo; Ozaki, Masanori

doi:https://doi.org/10.1063/1.4773519

Efficiency enhancement in mesogenic-phthalocyanine-based solar cells with processing additives

Dao, Quang Duy; Hori, Tetsuo; Hukumura, Kaoru et al.

Applied Physics Letters, 2012, 101(26), 263301-263301

Number of Access:624（2025-09-02 10:22 Counts）

Identifier to cite or link to this item: https://hdl.handle.net/11094/75666

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Title	Efficiency enhancement in mesogenic-phthalocyanine-based solar cells with processing additives
Creator	CreatorName Dao, Quang Duy
	CreatorName Hori, Tetsuo
	CreatorName Hukumura, Kaoru
	CreatorName Masuda, Tetsuya
	CreatorName Kamikado, Toshiya
	NRID 1000080304020 1000080304020 ORCID 0000-0003-3142-1193 0000-0003-3142-1193 researchmap permalink read0054804 read0054804 Scopus Author ID 35413649300 35413649300 CreatorName Fujii, Akihiko
	NRID 1000040357223 1000040357223 CreatorName Shimizu, Yo
	NRID 1000050204186 1000050204186 ORCID 0000-0002-9556-4225 0000-0002-9556-4225 researchmap permalink read0014092 read0014092 Scopus Author ID 55490143900 55490143900 CreatorName Ozaki, Masanori
Description	This article may be downloaded for personal use only. Any other use requires prior permission of the author and AIP Publishing. This article appeared in Quang Duy Dao, Tetsuro Hori, Kaoru Fukumura, Tetsuya Masuda, Toshiya Kamikado, Akihiko Fujii, Yo Shimizu, and Masanori Ozakii, Appl. Phys. Lett. 101, 263301 (2012) and may be found at https://doi.org/10.1063/1.4773519.
Abstract	Bulk heterojunction (BHJ) solar cells, fabricated by spin casting processes, with phase-separated small molecules including a phthalocyanine derivative, 1,4,8,11,15,18,22,25-octahexylphthalocyanine (C6PcH2), and a fullerene derivative, 1-(3-methoxy-carbonyl)-propyl-1-1-phenyl-(6,6)C61(PCBM), have been demonstrated to have a power conversion efficiency exceeding 4.1%. The C6PcH2:PCBM BHJ surface morphology and the phase separation have been controlled by utilizing processing additives in various solvents. The effects of the processing additives on the crystallization of the discotic C6PcH2 columns in hexagonal structures have been discussed. This work was partly supported by Grants-in-Aid for Scientific Research from the Ministry of Education, Culture, Sports, Science and Technology, Japan, and by Advanced Low Carbon Technology Research and Development Program from the Japan Science and Technology Agency (JST-ALCA).
Publisher	AIP Publishing
Source Title	Applied Physics Letters
Volume (Issue)	101(26)
Page	263301-263301
Date of Issued	2012-12-27
Language	English
Handle URL	https://hdl.handle.net/11094/75666
PISSN	00036951
eISSN	10773118
NCID	AA00543431
Relation.isIdenticalTo	DOI (Publisher Version) https://doi.org/10.1063/1.4773519
Access Rights	open access
oaire:version	Version of Record
Category	学術雑誌論文 Journal Article

Resource Type	journal article
Local Type	Journal Article
DCMI Type	Text
DCTERMS.bibliographicCitation	Applied Physics Letters. 2012, 101(26), p. 263301-263301
DC.title	Efficiency enhancement in mesogenic-phthalocyanine-based solar cells with processing additives
DC.creator	Dao, Quang Duy
	Hori, Tetsuo
	Hukumura, Kaoru
	Masuda, Tetsuya
	Kamikado, Toshiya
	Fujii, Akihiko
	Shimizu, Yo
	Ozaki, Masanori
DC.publisher	AIP Publishing
DC.language' scheme='DCTERMS.RFC1766	English
DC.type' scheme='DCTERMS.DCMIType	Text
DCTERMS.issued' scheme='DCTERMS.W3CDTF	2012-12-27
DC.identifier	https://doi.org/10.1063/1.4773519
DC.description	This article may be downloaded for personal use only. Any other use requires prior permission of the author and AIP Publishing. This article appeared in Quang Duy Dao, Tetsuro Hori, Kaoru Fukumura, Tetsuya Masuda, Toshiya Kamikado, Akihiko Fujii, Yo Shimizu, and Masanori Ozakii, Appl. Phys. Lett. 101, 263301 (2012) and may be found at https://doi.org/10.1063/1.4773519.
DCTERMS.abstract	Bulk heterojunction (BHJ) solar cells, fabricated by spin casting processes, with phase-separated small molecules including a phthalocyanine derivative, 1,4,8,11,15,18,22,25-octahexylphthalocyanine (C6PcH2), and a fullerene derivative, 1-(3-methoxy-carbonyl)-propyl-1-1-phenyl-(6,6)C61(PCBM), have been demonstrated to have a power conversion efficiency exceeding 4.1%. The C6PcH2:PCBM BHJ surface morphology and the phase separation have been controlled by utilizing processing additives in various solvents. The effects of the processing additives on the crystallization of the discotic C6PcH2 columns in hexagonal structures have been discussed. This work was partly supported by Grants-in-Aid for Scientific Research from the Ministry of Education, Culture, Sports, Science and Technology, Japan, and by Advanced Low Carbon Technology Research and Development Program from the Japan Science and Technology Agency (JST-ALCA).
DC.format	75666
citation_title	Efficiency enhancement in mesogenic-phthalocyanine-based solar cells with processing additives
citation_author	Dao, Quang Duy
	Hori, Tetsuo
	Hukumura, Kaoru
	Masuda, Tetsuya
	Kamikado, Toshiya
	Fujii, Akihiko
	Shimizu, Yo
	Ozaki, Masanori
citation_publisher	AIP Publishing
citation_language	English
citation_date	2012-12-27
citation_journal_title	Applied Physics Letters
citation_volume	101
citation_issue	26
citation_firstpage	263301
citation_lastpage	263301
citation_doi	https://doi.org/10.1063/1.4773519
citation_public_url	https://hdl.handle.net/11094/75666

Efficiency enhancement in mesogenic-phthalocyanine-based solar cells with processing additives

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