Silver(I) Sulfide Clusters Protected by Rhodium(III) Metalloligands with 3-Aminopropanethiolate

Yoshinari, Nobuto; Goo, Zi Lang; Nomura, Keisuke et al.

Inorganic Chemistry, 2023, 62(24), 9291-9294

Number of Access:474（2025-08-20 22:57 Counts）

Identifier to cite or link to this item: https://hdl.handle.net/11094/92439

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Title
Silver(I) Sulfide Clusters Protected by Rhodium(III) Metalloligands with 3-Aminopropanethiolate
Creator
NRID
1000010583338 1000010583338
ORCID
0000-0003-2457-0967 0000-0003-2457-0967
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Scopus Author ID
14009212400 14009212400
CreatorName
Yoshinari, Nobuto
CreatorName
Goo, Zi Lang
CreatorName
Nomura, Keisuke
CreatorName
Konno, Takumi
Description
Yoshinari N., Goo Z.L., Nomura K., et al. Silver(I) Sulfide Clusters Protected by Rhodium(III) Metalloligands with 3-Aminopropanethiolate. Inorganic Chemistry 62(24), 9291-9294, 19 June 2023, © 2023 American Chemical Society. DOI: 10.1021/acs.inorgchem.3c01309.
Abstract
The two homochiral AgIRhIII nanoclusters, Δ6/Λ6-[Ag11S{Rh(apt)3}6]9+ ([1]9+) and Δ6/Λ6-[Ag13S{Rh(apt)3}6]11+ ([2]11+), in which Ag11S and Ag13S cluster cores, respectively, are protected by fac-[Rh(apt)3] metalloligands, were newly synthesized from fac-[Rh(apt)3] (Hapt = 3-aminopropanethiol) and Ag+ in water in combination with sulfide sources. While [1]9+ was produced by using d-penicillamine as a sulfide source, the use of HS- as a sulfide source afforded [2]11+ without causing any precipitation of Ag2S. Cluster [1]9+ was convertible to [2]11+ via the reaction with Ag+, which led to a turn-on-type switch in photoluminescence from nonemissive [1]9+ to emissive [2]11+
Publisher
American Chemical Society
Source Title
Inorganic Chemistry
Volume (Issue)
62(24)
Page
9291-9294
Date of Issued
2023-06-19
Language
English
Handle URL
https://hdl.handle.net/11094/92439
PISSN
00201669
eISSN
1520510X
NCID
AA12097184
Relation.isVersionOf
DOI (Publisher Version)
https://doi.org/10.1021/acs.inorgchem.3c01309
Access Rights
open access
CopyRight
This document is the unedited Author’s version of a Submitted Work that was subsequently accepted for publication in Inorganic Chemistry, copyright © American Chemical Society after peer review. To access the final edited and published work see https://doi.org/10.1021/acs.inorgchem.3c01309.
oaire:version
Accepted Manuscript
Category
学術雑誌論文 Journal Article