Synthesis of Diarylselenides through Rh-Catalyzed Direct Diarylation of Elemental Selenium with Benzamides

Xu-Xu, Qing Feng; Nishii, Yuji; Miura, Masahiro

Journal of Organic Chemistry, 2022, 87(24), 16887-16894

Number of Access:344（2025-08-14 23:20 Counts）

Identifier to cite or link to this item: https://hdl.handle.net/11094/92806

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Title
Synthesis of Diarylselenides through Rh-Catalyzed Direct Diarylation of Elemental Selenium with Benzamides
Creator
CreatorName
Xu-Xu, Qing Feng
NRID
1000070773787 1000070773787
ORCID
0000-0002-6824-0639 0000-0002-6824-0639
researchmap permalink
y_nishii y_nishii
Scopus Author ID
55233363700 55233363700
CreatorName
Nishii, Yuji
NRID
1000020183626 1000020183626
ORCID
0000-0001-8288-6439 0000-0001-8288-6439
researchmap permalink
read0013936 read0013936
Scopus Author ID
7402799909 7402799909
CreatorName
Miura, Masahiro
Description
Xu-Xu Q.F., Nishii Y., Miura M.. Synthesis of Diarylselenides through Rh-Catalyzed Direct Diarylation of Elemental Selenium with Benzamides. Journal of Organic Chemistry. 87(24), 16887-16894, (2022), 16 December 2022; ©2022 American Chemical Society. https://doi.org/10.1021/acs.joc.2c02131.
Abstract
Diarylselenides are a representative class of molecules in organoselenium compounds. We herein report a Rh-cata-lyzed direct diarylation of selenium with benzamide derivatives. The use of elemental selenium as the Se source is intriguing in the view of atom economy, cost, stability, and handling. A series of diarylselenides with amide moieties were readily accessible through the directed C–H activation. The intermediacy of electrophilic Se(IV) species was indicated by the control experiments.
Publisher
American Chemical Society
Source Title
Journal of Organic Chemistry
Volume (Issue)
87(24)
Page
16887-16894
Date of Issued
2022-12-16
Language
English
Handle URL
https://hdl.handle.net/11094/92806
PISSN
00223263
eISSN
15206904
NCID
AA00704100
Relation.isVersionOf
DOI (Publisher Version)
https://doi.org/10.1021/acs.joc.2c02131
Access Rights
open access
CopyRight
This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of Organic Chemistry, © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.joc.2c02131.
oaire:version
Accepted Manuscript
Category
学術雑誌論文 Journal Article